System and method for conditioning and detection of moisture damage in asphalt mixes

ABSTRACT

An apparatus and method for determination of susceptibility of asphalt concrete materials to moisture damage. An asphalt sample of known bulk specific gravity (density) is placed inside a chamber filled with water, which is capable of heating the sample to a pre-determined temperature. The chamber is pressurized by introduction of air pressure to a flexible membrane that decreases the volume within a chamber containing the sample and water, increasing the pore pressure in the sample. The pressure is then released and allowed to come to ambient pressure. This process is repeated a predetermined number of times (cycles). When a selected number of cycles are complete, the asphalt sample is removed from the chamber and its bulk specific gravity (density) measured again. The difference between the density before and after conditioning is an excellent method of rating the degree at which moisture would deteriorate asphalt samples due to introduction of moisture. The cyclic nature of the increased/decreased pore pressure is observed to significantly decrease bulk specific gravity (density) for poor quality asphalt designs. Furthermore, the sample conditioned by this method can be used for other conventional mechanical test methods, such as tensile strength and modulus determination. Computerized controls are used to automate the procedure and to record and display data from sensors.

FIELD OF THE INVENTION

This invention relates generally to equipment and method for testingpavement mixes, commonly called asphalt, for the potential for waterdamage. More specifically, this relates to using water in a chamber thatis cyclically pressurized to simulate the action of water being pressedinto and pulled out of the wet pavement by tires on a roadway. Thecyclic pressure in the chamber containing the asphalt sample will causeloosening of the bond between individual aggregate particles formoisture susceptible mixtures and would significantly reduce themeasured density of the sample. Reduction in density is a good indicatorof moisture susceptibility of a mixture.

BACKGROUND OF THE INVENTION

Paving mixes known as asphalt consist of approximately 95 percentaggregates and five percent liquid binder. The mixture should bedesigned to create the best possible bond between the liquid binder andthe aggregate. Moisture can penetrate asphalt, which causes an adhesivefailure between the binder and the aggregate or water can soften oremulsify the binder film. In either case, water can reduce the strengthof the mixture of the asphalt. When the liquid binder is stripped fromthe asphalt, the aggregate can become scattered (called raveling) orlost. Loss of strength in mixtures can result in pot holes in thepavement or cracking or raveling or rutting.

It is well understood that moisture can strip the binder from theaggregates, resulting in a form of failure called “stripping” of anasphalt pavement. The cause of moisture damage to asphalt ismultifactorial. First, the type of aggregates used in the mixture affectthe susceptibility of the mixture with the binder to moisture damage.For example, residual clay left in aggregates after washing can cause aserious problem. Clay expands when it absorbs the water and creates abarrier between the aggregates and the binder effectively reducing theadhesion or cohesion of the bond between the binder and the aggregates.The composition of the binder also plays an important role in theresistance of the asphalt to moisture damage. The binder viscosity isaffected by the mixing temperature in the plant and the ingredients ofthe binder, such as polymers and rubbers, can also affect the ability ofthe binder to coat the aggregate surface and to keep the aggregatesbound. The binder emulsification has to be controlled to give strengthand resistance to moisture for the asphalt. The aggregates should bedried carefully at the plant. Typically, there should be no more than0.5% moisture retained in the plant produced mix. If water remains inthe aggregates, then, during the actual laying of the pavement, steamcan be produced which causes stripping of the binder from the aggregate.Controlling the amount of field compaction is necessary to reduce theamount of external water that can penetrate the pavement. A compactpavement with the optimum density and lack of air voids will reducewater permeability, hence reduce the possibility of water damage.However, compaction can be carried too far, which can cause rutting dueto mixture instability. If, during construction, there are layers ofasphalt mixtures, water can be trapped between the pavement layers.Segregation which is caused by aggregates gradation change when layingdown the pavement can have a detrimental affect on asphalt pavement andinduce moisture damage. Proper drainage is critical in design andconstruction of asphalt pavement. In many of these failure modes, thedensity of the compacted material is reduced. For example, as bondstrength between individual aggregate particles is reduced, the mixturewill tend to lose strength and additional air channels are createdwithin the compacted mixture, which correlates to the drop in density.

It is apparent, from the above discussion, that susceptibility to waterdamage or stripping to an asphalt pavement can arise from many sources.Even an ideal mixture of binder and aggregate properly processed orinstalled can still be susceptible to water damage. Evaluation ofmoisture susceptibility has become an important part of volumetricdesign procedure and pavement construction quality control. However, themost important test to determine the susceptibility of water damage foran asphalt mixture requires testing the compacted asphalt mixture in away that will predict susceptibility of that compacted mixture to waterdamage.

In our previous U.S. Pat. No. 6,799,471, a two tank system was used toapply moisture damage to the asphalt concrete specimens. This devicerequired a source of high flow pressurized air. As one tank is opened tothe air, the other would be pressurized and maintain pressure whileforcing water to the other tank through a restricted valve. Once thewater reached a certain level, the pressurized tank would open and theopen tank would be pressurized forcing the water back the other way. Adrawback to this device was that it required a large amount of valvingand a pump to keep the water circulating. Another drawback was thisdevice was bulky for field laboratories and its repeatability was highlydependent on the air supply available at each lab. The most widely usedtest for moisture sensitivity is covered under American Association ofState Highway and Transportation Official (AASHTO) specification T283and American Society of Testing and Materials (ASTM) D4867. In both ofthese methods 2 sets of samples of asphalt of approximately 6 inch indiameter by 4 inch thickness are compacted to 7% air voids in laboratorycompaction equipment. Air voids is determined by the ratio of thecompacted sample density to the maximum density of the mixture. Thecompacted sample density and maximum density of the mixture can bedetermined based on standard test methods used in asphalt laboratories.The mixture can be prepared in the laboratory or can be obtained from afield site. One set is saturated with water and is kept in a temperaturecontrolled water bath at 60 degree C. for 17 to 24 hours. The controlset is kept at room temperature (25 degree C.). In some situations (coldclimates), the sample set is also kept at degree C. for extended time toprovide a climatic cycle of cold to hot. Both conditioned (sample) andunconditioned (control) sets are then placed in a break press and brokento determine the pressure at which the sets break apart. The ratio ofunconditioned (control) to conditioned (sample) sets break pressure isthen used to determine the sensitivity of the mixture to moisturedamage. If this ratio (Conditioned sample strength/Unconditioned samplestrength) is over 70, then the mixture passes this test and is deemedacceptable. A visual inspection of the broken conditioned sample mayreveal adhesion loss and provide useful information in the inspectionstage. The acceptance ratio varies and can range from 70 to 85 dependingon the agency and the mixture type. Unfortunately, the reliability andrepeatability of this test is very poor, the test does not simulate thetrue dynamics of the field conditions and the results cannot becorrelated to the actual field performance. Furthermore, this test doesnot effect any change in the density of the sample and the only effectcaused by this test could be at the molecular level.

In an attempt to create pore pressure within a compacted sample and tobetter emulate the actual field conditions, in 1974, Rudy Jimenez ofArizona introduced the Double Punch method. This method included acompacted sample that was held under load by a punch or a plate from topto bottom of the sample. The sample was kept under water and asinusoidal load (5-30 psi) was applied to the sample repeatedly. Eventhough this method could introduce pore pressure within the sample, itstill did not simulate the actual dynamics of the water movement in andout of the pavement through tire activity. Furthermore, the testing timeis too long with sophisticated equipment and does not correlate to fieldperformance.

Recently, wheel rutting devices have been used to predict stripping andmoisture damage. These devices use a small wheel that travels back andforth on a compacted sample that is immersed in 50° C. water. Force isapplied to the wheel in various amounts. Although these devices canpredict the rutting rate in the pavement, the results have not beencorrelated to stripping or moisture damage.

Another system that has been used in research is called an EnvironmentalConditioning Chamber (ECS). This device was developed at Oregon StateUniversity in 1987. In this test, a sample is placed in a chamber filledwith 60° C. water and confining pressure of 2.5 in Hg. A conditioningdirect load of 200 lbs. is applied on the sample for 0.1 sec. and thenreleased for 0.09 sec. In this device the resilient modulus of thesample is measured before and after the loading/conditioning process.Empirical criteria is developed based on performance of known mixes toestablish pass/fail limits for moisture damage. Unfortunately, this testtakes 6-18 hours and so far has had poor repeatability. Also, theapparatus needed to conduct this test is extremely expensive and largefor a typical laboratory application in the construction industry. Thisapparatus is mainly used for research and is not widely available.

Harris et al., U.S. Pat. No. 5,987,961, discloses an apparatus fortesting asphalt. Rollers are driven over a pair of pavement samplesplaced in trays beneath the wheels. The samples are placed in trayswhich are in a water bath. It is controlled by a computer whichcontinuously monitors where the pavement sample is by a displacementtransducer. Terrell et al., U.S. Pat. No. 5,365,793, discloses anasphalt sample in a sealed container. A pressure differential is createdacross the asphalt and passes water or air or a mix through the asphaltsample by the differential pressure between the vacuum and the supply offluid which flows through the specimen. For the Terrell device, atypical test procedure will take more than twelve hours.

A study was conducted by University of Florida in June of 2005, titled“Development and Evaluation of Test Methods to Evaluate Water Damage andEffectiveness of Anti-Stripping Agents”. This method consists of amoisture saturated sample confined in a rubber membrane submerged inwater under a fixed pressure. A cyclic physical load is then applied tothe sample by means of plates attached to a piston, while watersurrounding the sample remains under constant pressure and temperature.This device applies a physical pressure (squeeze) to the sample. Thecyclic squeezing action of the sample creates a pore pressure within thesample. The physical load on the sample in the Florida study onlyeffects small pore volume changes in the sample and dependssignificantly on the type and characteristics of the mixture. Thisdevice requires a significant amount of floor space and is too expensivefor normal asphalt laboratories.

Despite this earlier work it would be an advance in the art to providean instrument and testing method that can be used during design andquality control to determine the stripping potential and moisturesusceptibility of an asphalt mix. The device should use pressure cyclesin which water is forced in and then drawn out of the pores in asphalt.The device should be simple to operate, small so that it would fitinside normal field construction labs and provide an evaluation method,such as density difference, that is practical and can be tested before,during and after the construction of asphalt pavements. All asphaltlaboratories are equipped with instruments for measurement of bulkdensity. Bulk density tests are performed with standard test methodsreadily available in the industry and one can produce results in lessthan five minutes. Sample density can be measured before and aftermoisture sensitivity test and any decrease in density can be directlycorrelated to the sensitivity and quality of the asphalt mixture. Thetesting time should be relatively short in time. It should producerepeatable results and should be capable of testing field and laboratoryfabricated samples of any size.

SUMMARY OF THE INVENTION

The current invention subjects an asphalt sample to the wear behavior ofwet road paving materials subjected to the stresses from the tire loadsproduced by vehicular traffic. When a tire rolls on a wet asphaltsurface the material is subject to three phases of stresses, an initialpressure phase where tire initially makes contact with the surface andthe water is forced into the pores of the asphalt creating large porepressures, a relaxation phase where the tire is in contact with the roadfor a period of time and the water begins to disperse beneath the tire,and a reverse pressure phase where the surface of the tire leaves thesurface of the asphalt road. The current invention is used to evaluatethe quality of asphalt design by speeding up the process using anelevated temperature and repetitively applying and releasing pressure inorder to subject the sample to the action of a tire on an asphaltpavement surface. Poor asphalt will reflect this by showing a decreasein bulk specific gravity (density) of the sample when comparing thedensity from before to after the test. In a moisture susceptiblepavement, pore pressure weakens the bond between the individual rocks,which causes loosening of the bond between individual aggregateparticles and is correlated to a drop in the density and eventual causefor raveling of rocks, moisture damage to the roadway and pot holes.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows one embodiment of the invention demonstrating the operationof the pressure application process.

FIG. 2 shows a detailed view of the sample container and a diaphragmused to transfer the pressure to the water.

FIG. 3 shows several different void structures in an Asphalt concretesample.

DETAILED DESCRIPTION OF THE DRAWINGS

FIG. 1 shows the preferred embodiment of the moisture damage inducingdevice (100). Sample (101) of known density is placed into a sealabletank (102) filled with water and rests on internal support (120). Thedensity can be measured by water displacement method or other methodsroutinely employed for determination of sample density. Standard methodsfor measurement of density are specified under ASTM test methods D2726and D6752. Before placing the conical lid (126) on the tank (102) andsealing the tank (102) residual air has to be removed from the tank(102). If too much air is left in the tank (102), it will be difficultto achieve high pressures inside the tank (102). If residual air existsin the pores of the sample (101), the air may become dislodged and risein the tank (102). This air may be bled from the system by using theconical shape on the inside surface of the conical lid (126). Theconical lid (126) will allow the air to move to the tip of the cone,where a bleed valve (123) is placed. The bleed valve (123) can becontrolled electronically by using an ASCO valve (Florham Park, N.J.),which can be opened and closed through computer commands. Additionally,a water reservoir (122) is used to fill the tank (102) to its capacity,once any residual air is removed from the tank (102). The reservoir(122) can also be controlled by using electronic water valve (125) andcomputer controls. In operation, the moisture damage inducing device(100) is allowed to run at high pressure for a few cycles. The moisturedamage inducing device (100) is then stopped and the bleed valve (123)is opened to let residual air out and then closed. The water reservoirvalve (125) is opened and the tank (102) is filled to capacity. Thereservoir (122) is placed above the sealable tank (102) and willautomatically replenish the water in the sealable tank (102) by theamount of air space available. This process is repeated multiple timesbefore the start of the test to make sure all residual air is removedfrom the sealable tank (102). The entire process is controlled throughsoftware. Obviously, this air bleeding process can also be accomplishedmanually by opening a hand operated bleed valve after a few cycles,letting air out and using a syringe or other water containers to backfill the tank with water. Once the air bleeding process is complete,heater (110) will continue raising the water temperature to the desiredlevel. Once the set temperature is reached, active air cylinder (105)with sensors (121) to detect piston position, moves up reducing thetotal connected volume (112) of passive air cylinder (103), volume (113)of the active cylinder (105), and volume (113) of the expandablemembrane (104). Pressure increases as the volume (113) of activecylinder (105) is reduced. Water in tank (102) is separated from air inthe expandable membrane (104). The expandable membrane (104), inintimate contact with the water in the tank (102), transmits thepressure to the water in tank (102) thereby applying pressure to poresin sample (101).

An adjustment mechanism (107) is to be used to adjust the pressuresealable tank (102). The adjustment mechanism (107) increases ordecreases the volume (112) of the passive air cylinder (103). Thevolumes of the passive air cylinder (103), the inflatable bladder (104),and the active air cylinder (105) are connected. By decreasing thevolume (112) of the passive air cylinder (103) enables more air to beforced into the expandable membrane (104) as the volume (113) of theactive air cylinder (105) is decreased. In the active air cylinder(105), a piston (105A) is driven by the hydraulic piston (118). Ashydraulic fluid is forced into one end of piston (118) connected tohydraulic piston shaft (114) the hydraulic piston shaft (114) forces thepiston (105A) upward causing the volume (113) in the active cylinder(105) to decrease. Switch (119) is activated. Hydraulic fluid fromreservoir (109) is forced into the other end of the hydraulic piston(118) reversing the direction of the piston and increasing the volume(113). A motor (115) turns the pump (117), forcing hydraulic fluid froma reservoir (109) into the hydraulic piston (118). As hydraulic fluid isforced into one end of piston (118) connected to the hydraulic pistonshaft (114), the hydraulic piston shaft (114) forces the piston (118)upward causing the volume (113) in the active cylinder (105) todecrease. When switch (119) is activated, hydraulic fluid from thereservoir (109) is forced into the other end of the hydraulic piston(118) reversing the direction of the piston (118) movement andincreasing the volume (113). As the volume of (113) decreases, volume ofair in the expandable membrane (104) increases, forcing water in thesealable tank (102) into the sample (101). Maximum pressure is obtainedwhen the volume (113) of the active cylinder (105) is transferred to thevolume (111) of the inflatable bladder (104) and the volume (112) of thepassive air cylinder (103) is at a minimum by using the adjustingmechanism (107). When the active piston (105A) is at the bottom of adownstroke, a control (121) opens valve (106) to allow air in thepassive air cylinder (103), the expandable membrane (104), and theresidual volume (111) to equalize with atmospheric air. This assuresthat at the beginning of the upstroke of the piston (105) the airpressure is ambient air pressure in the active cylinder (105), thepassive cylinder (103), and the expandable membrane (104). It can bereadily seen that the active piston (105A) can be driven up and down bythe hydraulic piston (118). Motion of the piston (118) can continue in acycling fashion alternately applying pressure to the sample (101) andrelieving the pressure applied to the sample (101). Those skilled in theart will recognize other means of applying pressure using other kinds ofactuating mechanisms. Hydraulic, pneumatic, linear motor, or rotarymotors are examples not shown which will also serve the purpose ofdriving the active piston (105A) to apply pressure in the sample. At theend of a predetermined number of cycles, the sample is removed and itsdensity measured by standard testing methods such as ASTM D2726 or ASTMD6752. Decrease of more than 0.5% in density from before to after thecyclic moisture sensitivity test has shown a strong correlation to weakmoisture performance mixtures on the roadway. Unlike methods such as thedouble punch method or the wheel rutting method, no physical force isapplied to the asphalt mix. Physical contact from a wheel or a punchtends to compact the mixture increasing its density and make itimpossible to determine the susceptibility to water damage by densitytesting.

FIG. 2 shows a detailed view preferred embodiment of sealable tank(102). Flexible membrane (104), flexible membrane ring guard (201), andflexible membrane support (202) show the mechanism for transferringexternally applied pressure to the internal volume of sealable tank(102) and to sample (101) of sealable tank (102). Flexible membrane(104) is fastened to flexible membrane support (202) which rests on tankbottom (204). Flexible membrane (104) has a diameter such that ringguard (201) rests completely on flexible membrane (104) securely toflexible membrane support (202). Flexible membrane ring guard (201) issecured to flexible membrane support (202) by fasteners (206). Flexiblemembrane (104) is made of a flexible and expandable material so that aspressure increases in volume (111), it expands to account for smallresidual air not completely removed from inside sealable tank (102) andinside sample (101) but is prevented from further expansion by theincompressibility of water. Those skilled in the art will recognize thatthere are other ways to accomplish the result of flexible membrane(104), flexible membrane support base (202), and flexible membrane ringguard (201). These include but are not limited to applying the flexiblering guard (201) directly to sealable tank bottom (204) to restrainflexible membrane (104), replacing flexible membrane (104), flexiblemembrane support base (202), and flexible membrane ring guard (201) witha single rubber bladder.

A critical element of sealable tank (102) is the design of the conicallid (126) in order to reach a desired pressure setting and applicationof consistent pressure from one cycle to the next. It is important thatair trapped inside the sealable tank (102) be removed. The underside ofconical lid (126) has an upward slope toward the center of the conicallid (126). Any residual air inside sealable tank (102) will move up andbecause of the slope on conical lid (126) will subsequently move to thecenter of conical lid (207) where it can be removed by bleed valve (123)thereby assuring maximum and consistent pressure is achieved.

FIG. 3 depicts an asphalt core. As mentioned above moisture damage toasphalt is multifactorial, however FIG. 3 depicts a sample (300) withdifferent void structures. Void (301) shows a void lying next toaggregate (305). Void (304) represents a void that may be semi-connectedand does not fully saturate until pressure is applied. Void (303) is aninterconnected void that makes its way from the surface and meandersback to the same surface. All these voids will react differently toapplied pressure, void (301) may cause the binder to separate from theaggregate allow water to infiltrate into the voids themselves. Asmentioned above if clay is present an expansion may take place. A voidsuch as (304) may allow an agitating motion of the water as pressure isapplied and removed resulting in an emulsifying condition and expandingthe pore size. As repetitive cyclic pressure is applied, bond betweenindividual aggregate will weaken and break. The loosening and break inbond between aggregates will create additional voids, crack and airchannels with compacted mixtures. The additional air volume within themixture will decrease the density of the cpmpacted mixture. Mixtureswith strong bond will suffer very little change in density. However,density of poor and moisture susceptible mixture will reducesignificantly. The apparatus and method of this invention will providean easy, inexpensive, and practical method for measurement of moisturesusceptibility in the laboratories. The conditioning method is automaticwith little operator involvement and the density measurement changeproposed for determination of moisture sensitivity is simple and can beperformed with existing equipment already available in almost allasphalt laboratories.

Theory and Data:

The action of the device can be understood from the ideal gas law, morespecifically Boyle's Law. Where given an initial volume Vi, an initialpressure pi, a final pressure Pf, and a final volume V f therelationship between these variables is given below.

P_(i)V_(i)=p_(f)V_(f)

In the case cited above we must identify the volumes before anyquantitative analysis may be accomplished. For the initial volume Vi wehave the following:

-   Via=initial volume (113) of the active cylinder (105),-   Vip=initial volume (112) of the passive cylinder (103),-   Vir=initial unknown residual volume in tank (102),-   Vis=initial unknown residual volume in sample (101),-   Vib=initial volume (111) of flexible membrane (104).    For the final volume Vf we have the following:-   Vfa=final volume (113) of the active cylinder (105),-   V fp=final volume (112) of the passive cylinder (103),-   Vfr=final unknown residual volume in tank (102),-   V fs=final unknown residual volume in sample (101),-   V fb=final volume (111) of flexible membrane (104).

The quantities we know are V fa which we will take to be zero, and V fpwhich is equal to Vip and will simply be denoted as V p, and Vib whichwe take to be zero. Our equation becomes:

p _(i)(V _(ia) +V _(p) +V _(ir) +V _(is))=p _(f)(V _(p) +V _(fr) +V_(fs) +V _(fb))

From this we see that the final pressure we are able to obtain isdetermined by residual tank volume Vir, the volume Vis of the samplevolume. If we are able to saturate the sample completely and remove allresidual air the equation simplifies to the one below.

p _(i)(V _(ia) +V _(p))=p _(f)(V _(p))

Note that volume (111) of flexible membrane (104) does not appear sincewater is incompressible and there are no compressible air voids. Lookingat equation above it is simple to observe that if the initial volume(113) of the active cylinder (105) is equal to volume (112) of passivecylinder (103) then the absolute pressure increases to twice theoriginal value. If sample (101) is fully saturated then it experiencesthat pressure against it's internal structure which was manufactured atnormal atmospheric pressures.

The current method, American Association of State Highway andTransportation Official (AASHTO) specification T283, moisturesensitivity is to measure the tensile strength at which a conditionedsample breaks compared to an unconditioned sample and do a visualinspection to identify the degree of stripping. Results from testingsamples conditioned using the current invention to apply cyclic pressureloads under heated conditions indicate that poor asphalt samples whichare susceptible to moisture damage and stripping suffer a reduction inbulk specific gravity (density) compared to the original bulk specificgravity (density). A reduction of 0.5% in bulk specific gravity(density) has shown good correlation to roadway mixtures that are weakand susceptible to moisture damage. Data from several differentmaterials tested is shown in the table below.

Data Using the Apparatus of the invention Cycles 10,000, Temperature 60C Density Density Condition Before after Pass/ Sample Pressure ConditionCondition fail Number (psi) (g/cm3) (g/cm3) % Diff Criteria 1 42 2.2502.173 3.4 Fail Marginal Mix 2 42 2.251 2.206 −2.0 Fail Marginal Mix 3 452.469 2.471 +0.08 Good mix 4 45 2.468 2.471 −0.12 Good mix

The samples tested in the table above are mixes used in North Carolina.The apparatus and method disclosed in this invention was used fortesting the above samples. The accepted test method in North Carolinafor moisture susceptibility of mixtures is AASHTO T283. This testexamines the tensile strength ratio (FSR) of samples that have beenconditioned at 60° C. for 24 hours versus samples that have not beenconditioned. This test indicated TSR of above 90% for materials used insample 1 and 2. TSR of 80% and higher are deemed acceptable under therequirements of most states. However, this mixture failed after 3 weeksin service due to moisture damage. The results obtained from the currentinvention (above table) showed a significant drop in density for samplesof moisture susceptible mixtures conditioned by this invention. Usingthe results obtained from the method of this invention would haveprevented these mixtures from being applied in the field and would havesaved millions of dollars in removal and replacement of these mixtures.

1. An apparatus to treat an asphalt sample for detection ofsusceptibility to moisture damage for asphalt mixes comprising: (a) atleast one chamber, said chamber openable and closeable for receipt of asample of compacted asphalt mix therein, with chamber sealable whenclosed; (b) means for removing air from said chamber; (c) means forfilling said chamber with water; (d) means for cyclically applyingpressure to said chamber; whereby cycles of pressure are applied to saidcompacted asphalt mix induce physical changes therein.
 2. An apparatusto treat an asphalt sample for detection of susceptibility to moisturedamage for asphalt mixes of claim 1 wherein said means for removing airfrom said chamber comprises a bleed valve and means for directing aid tosaid bleed valve.
 3. An apparatus to treat an asphalt sample fordetection of susceptibility to moisture damage for asphalt mixes ofclaim 2 wherein said means for directing residual air is a cone shapedlid used to seal said chamber and said bleed valve for said chamber ispositioned at the apex of said cone shaped lid.
 4. An apparatus to treatan asphalt sample for detection of susceptibility to moisture damage forasphalt mixes of claim 1 further comprising a heater for heating anywater introduced to said chamber.
 5. An apparatus to treat an asphaltsample for detection of susceptibility to moisture damage for asphaltmixes of claim 1 wherein said means for cyclically applying pressure tosaid chamber is at least an expandable membrane; said expandablemembrane positioned inside said chamber whereby when said expandablemembrane is expanded it applies pressure to water in said chamber toapply pressure to pores in an asphalt mix contained in said chamber. 6.A method to treat an asphalt sample for detection of susceptibility tomoisture damage for asphalt mixes comprising means for detectingphysical changes in said compacted asphalt mix.
 7. A method to treat anasphalt sample for detection of susceptibility to moisture damage forasphalt mixes comprising: (a) placing a sample of asphalt mix in a testchamber; (b) adding water to said test chamber containing a sample ofasphalt mix therein; (c) decreasing the volume of said chamber byexpanding an expandable membrane in said chamber thereby pressurizingwater in said test chamber; (d) bleeding air from said chamber; (e)adding more water to said chamber to replace said air bled from saidchamber; (f) pressurizing said test chamber after air is bled from saidtest chamber whereby said method forces residual air from said chamberand said asphalt mix and applies pressure to pores in said sample ofasphalt mix in said chamber inducing physical changes in said sample. 8.A method to treat an asphalt sample for detection of susceptibility tomoisture damage for asphalt mixes of claim 7 further comprisingproviding a cone shaped lid with a bleed valve at the apex of said coneshaped lid for said chamber whereby said bleed valve may be used tobleed air from said chamber during expansion of said expandablemembrane.
 9. A method to treat an asphalt sample for detection ofsusceptibility to moisture damage for asphalt mixes of claim 8 furthercomprising providing a heater for heating water introduced to saidchamber.
 10. A method to treat an asphalt sample for determination ofsusceptibility of asphalt samples to moisture damage comprising: (a)saturating an asphalt sample of a first known density with water; (b)introducing said sample to a chamber at least partially filled withwater; (c) increasing pressure inside said chamber while bleeding airfrom said chamber; (d) adding water to said chamber; (e) increasingpressure in said chamber a predetermined number of times; (f) removingsaid asphalt sample from said chamber and measuring a second densityafter said predetermined cycles and comparing said second density tofirst known density of said asphalt.
 11. A method to treat an asphaltsample for determination of susceptibility of asphalt samples tomoisture damage of claim 10 further providing a cone shaped lid on saidchamber.
 12. A method to treat an asphalt sample for determination ofsusceptibility of asphalt samples to moisture damage of claim 11 furtherproviding on said cone shaped lid a bleed valve whereby said cone shapedlid directs air toward said bleed valve and said bleed valve bleeds airfrom said chamber.
 13. A method to treat an asphalt sample fordetermination of susceptibility of asphalt samples to moisture damage ofclaim 12 including further providing a heater for heating waterintroduced into said chamber.
 14. A method to treat an asphalt samplefor determination of susceptibility of asphalt samples to moisturedamage of claim 10 further comprising providing a pump and driveassembly to cyclically inflate and deflate an inflatable membranethereby producing repetitive applications of cyclical pressure in saidchamber.
 15. A method to treat an asphalt sample for determination ofsusceptibility of asphalt samples to moisture damage of claim 14 whereinsaid step of providing a pump and drive assembly further comprisesproviding a rubber bladder as said inflatable membrane.
 16. A method totreat an asphalt sample for determination of susceptibility of asphaltsamples to moisture damage of claim 14 wherein said step of providingpump and drive assembly further comprises providing an enclosed chamberwith flexible rubber on at least one surface as said flexible membrane.17. A method for determination of susceptibility of a compacted asphaltsample to moisture damage by measuring density before and aftertreatment with pressurized water, without mechanical pressure applied tosaid compacted asphalt sample, comprising: (a) measuring a first densityof a compacted asphalt sample; (b) providing a means for subjecting saidcompacted asphalt sample to at least one cycle of pressurized water; (c)measuring a second density of said compacted asphalt sample; (d)comparing it to said first density; whereby a difference in said firstand said second density provide an accurate means of predicting thesusceptibility of said compacted asphalt sample to moisture damage. 18.A method for determination of susceptibility of a compacted asphaltsample to moisture damage by measuring density before and aftertreatment with pressurized water, without mechanical pressure applied tosaid compacted asphalt sample, of claim 17 wherein said providing ameans for subjecting said compacted asphalt sample to at least one cycleof pressurized water comprises a chamber open and closeable for receiptof a sample of compacted asphalt mixed therein, means for removing airfrom said chamber, means for filling said chamber with water, and meansfor cyclically applying pressure to said chamber.
 19. A method fordetermination of susceptibility of a compacted asphalt sample tomoisture damage by measuring density before and after treatment withpressurized water, without mechanical pressure applied to said compactedasphalt sample, of claim 18 wherein said providing said means forremoving air from said chamber comprises providing a bleed valve andcone-shaped lid on said chamber.
 20. A method for determination ofsusceptibility of a compacted asphalt sample to moisture damage bymeasuring density before and after treatment with pressurized water,without mechanical pressure applied to said compacted asphalt sample, ofclaim 19 which further comprises providing a heater for heating anywater introduced to said chamber.